venpay, please try this:
1) at PythonAnywhere - create again the webapp (for domain www.venpay.net) if you deleted it. Then you should get a new webapp number and DNS name. I have suspicion, that your previous "webapp-410264" would not work anymore if deleted.
2) at HostingSSi - edit DNS settings and also add the dot "." to the end of CNAME, like this:
"webapp-XXXXXX.pythonanywhere.com." (the XXXXXX will be your new PA webapp number)
P.S. How can I help you, if you seem not willing to cooperate? :) I can guess, if your webapp is offering payment services, next step you'll need - add the HTTPS encryption. This is even a bit more complicated than creating a proper CNAME in DNS, you may need help again.